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By Michael P. Doyle

Presents the main cutting edge ends up in carbene chemistry, atmosphere the basis for brand new discoveries and applications

The discovery of reliable carbenes has reinvigorated carbene chemistry learn, with investigators looking to improve carbenes into new worthwhile catalysts and ligands. featuring the main cutting edge and promising parts of carbene study during the last decade, this ebook explores newly chanced on structural, catalytic, and organometallic facets of carbene chemistry, with an emphasis on new and rising artificial applications.

Contemporary Carbene Chemistry good points contributions from a global group of pioneering carbene chemistry researchers. jointly, those authors have highlighted the main attention-grabbing and promising parts of research within the box. The ebook is split into parts:

  • Part 1, houses and Reactions of Carbenes, explores new findings on carbene balance, acid-base habit, and catalysis. Carbenic constitution and reactivity are tested in chapters devoted to solid carbenes, carbodicarbenes, carbenes as visitors in supramolecular hosts, tunneling in carbene and oxacarbene reactions, and ultrafast kinetics of carbenes and their excited country precursors. Theoretical matters are addressed in chapters on computational equipment and dynamics utilized to carbene reactions.
  • Part 2, steel Carbenes, is devoted to the factitious dimensions of carbenes, relatively the reactions and catalytic houses of steel carbenes. The authors speak about lithium, rhodium, ruthenium, chromium, molybdenum, tungsten, cobalt, and gold.

All the chapters finish with a precis of the present state of affairs, new demanding situations at the horizon, and promising new learn instructions. a listing of key stories and proposals for extra examining additionally accompanies each chapter.

Each quantity of the Wiley sequence on Reactive Intermediates in Chemistry and Biology makes a speciality of a particular reactive intermediate, supplying a huge diversity of views from prime specialists that units the degree for brand spanking new purposes and extra discoveries.

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